33. Diastereoselective C–H Bond Amination for Disubstituted Pyrrolidines.

Iovan, D. A.; Wilding, M. J. T.; Baek, Y.; Hennessy, E. T.; Betley, T. A. Angew. Chem. Int. Ed., 2017, 56, 15599.


32. Direct Comparison of C–H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.

Wilding, M. J. T.; Iovan, D. A.; Wrobel, A. T.; Lukens, J. T.; MacMillan, S. N.; Lancaster, K. M.; Betley, T. A. J. Am. Chem. Soc., 2017, 139, 14757.


31. Reactivity of a stable copper-dioxygen complex.

Iovan, D. A.; Wrobel, A. T.; McClelland, A. A.; Scharf, A. B.; Edouard, G. A.; Betley, T. A. Chem. Commun., 2017, 53, 10306.


30. High spin iron imido complexes competent for C-H bond amination

Wilding, M. J. T.; Iovan, D. A.; Betley, T. A. J. Am. Chem. Soc., 2017, 139, 12043.


29. C-H Activation from Iron(II)-Nitroxido Complexes

Kleinlein, C.; Bendelsmith, A. J.; Zheng, S.-L.; Betley, T. A. Angew. Chem. Int. Ed., 2017, 56, 1.


28. Ground State and Excited State Tuning in Ferric Dipyrrin Complexes Promoted by Ancillary Ligand Exchange

Kleinlein, C.; Zheng, S.-L.; Betley, T. A. Inorg. Chem., 2017, 56, 5892.


27. Characterization of Iron–Imido Species Relevant for N–Group Transfer Chemistry

Iovan, D. A.; Betley, T. A. JACS, 2016, 138, 1983.


26. Maximizing Electron Exchange in a [Fe3] Cluster

Hernández Sánchez, R.; Bartholomew, A. K.; Powers, T. M.; Ménard , G.; Betley, T. A. JACS, 2016, 138, 2235.


25. Meta-Atom Behavior in Clusters Revealing Large Spin Ground States

Hernández Sánchez, R.; Betley, T. A. JACS, 2015, 137, 13949.


24. Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L')m]n+ Clusters

Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. JACS, 2015 , 137, 11126.


23. Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n=0, −1)

Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. Angew. Chem. Int. Ed., 2015, 54, 12009.


22. Iron-mediated Intermolecular N-Group Transfer Chemistry with Olefinic Substrates

Hennessy, E.T.; Liu, R.Y.; Iovan, D.A.; Duncan, R.A.; Betley, T.A. Chem. Sci., 2014, 5, 1526.



21. Multiple, Disparate Redox Pathways Exhibited by a Tris(pyrrolido)ethane Iron Complex

Sazama, G.T.; Betley, T.A. Inorg. Chem., 2014, 53, 269.



20. Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters

Powers, T.M; Gu, N.X.; Fout, A.R.; Baldwin, A.M.; Hernández Sánchez, R.; Alfonso, D.M.; Chen, Y.; Zheng, S.; Betley, T.A. JACS, 2013, 135, 14448.



19. Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites

Powers, T.M.; Betley, T.A. JACS, 2013, 135, 12289.



18. Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

Hennessy, E.T.; Betley, T.A. Science, 2013, 340, 591.



17. Metal Atom Lability in Polynuclear Complexes

Eames, E.V.; Hernández Sánchez, R.; Betley, T.A. Inorg. Chem, 2013, 52(9), 5006.



16. Co(III) Imidos Exhibiting Spin Crossover and C–H Bond Activation

King, E.R.; Sazama, G. T.; Betley, T.A. JACS, 2012, 134, 17858.



15. Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure

Fout, A.R.; Xiao, D.J.; Zhao, Q.; Harris, T.D.; King, E.R.; Eames, E.V.; Zheng, S.; Betley, T.A. Inorg. Chem., 2012, 19, 10290.



14. Site-Isolated Redox Reactivity in a Trinuclear Iron Complex

Eames, E.V.; Betley, T.A. Inorg. Chem., 2012, 19, 10274.



13. Modulation of magnetic behavior via ligand-field effects in the trigonal clusters (PhL)Fe3L*3 (L* = thf, py, PMe2Ph)

Eames, E.V.; Harris, T.D.; Betley, T.A. Chem. Sci., 2012, 3, 407.


12. Oxidative Atom-Transfer to a Trimanganese Complex To Form Mn66-E) (E = O, N) Clusters Featuring Interstitial Oxide and Nitride Functionalities

Fout, A.R.; Zhao, Q.; Xiao, D.J.; Betley, T.A. JACS, 2011, 133(42), 16750.


11. Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6 Cluster with a Dramatically Expanded Octahedral Core

Harris, T.D.; Betley, T.A. JACS, 2011, 133(35), 13852.


10. Reductive Coupling of CO Templated by Iron Bound to the Tris(pyrrolide)ethane Scaffold

Sazama, G.T.; Betley, T.A. Organometallics, 2011, 30(16), 4315.


9. Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso-Fluoroarylation

Scharf, A.B.; Betley, T.A. Inorg. Chem., 2011, 50(14), 6837.


8. Expanded redox accessibility via ligand substitution in an octahedral Fe6Br6 cluster

Harris, T.D.; Hernandez Sanchez, R.; Betley, T.A. Chem. Commun., 2011, 47, 6344.


7. [(HL)2Fe6(NCMe)m]n+ (m = 0, 2, 4, 6; n = −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe6 Clusters Supported by a Hexaamide Ligand Platform

Zhao, Q.; Harris, T.D.; Betley, T.A. JACS, 2011, 133(21), 8293.


6. Catalytic C-H Bond Amination from High-Spin Iron Imido Complexes

King, E.R.; Hennessy, E.T.; Betley, T.A. JACS, 2011, 133(13), 4917.


5. Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride, [Fe33-N)]

Powers, T.M.; Fout, A.R.; Zheng, S.L.; Betley, T.A. JACS, 2011, 133(10), 3336.


4. Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe–Fe Interactions

Dr. Qinliang Zhao, Prof. Theodore A. Betley ACIE, 2011, 50(3), 709.


3. Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion

Sazama, G.T.; Betley, T.A. Inorg. Chem., 2010, 49(5), 2512.


2. Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands

King, E.R.; Betley, T.A. JACS, 2009, 131(40), 14374.


1. C−H Bond Amination from a Ferrous Dipyrromethene Complex

King, E.R.; Betley, T.A. Inorg. Chem., 2009, 48(6), 2361.

Electronic Design Criteria for O—O Bond Formation via Metal Oxo Complexes (Special Oxygen Forum Issue)
Betley, T. A.; Wu, Q.; Van Voorhis, T.; Nocera, D. G. Inorg. Chem., 2008, 47, 1849-1861.

A Ligand Field Chemistry of Oxygen Generation by the Oxygen-Evolving Complex and Synthetic Active Sites
Betley, T. A.; Surendranath, Y.; Childress, M. V.; Alliger, G. E.; Fu, R.; Cummins, C. C.; Nocera, D. G. Phil. Trans. R. Soc. B., 2008, 363, 1293-1303.

XAS Characterization of a Nitridoiron(IV) Complex with a Very Short Fe—N Bond
Rhode, J.-U.; Que, L., Jr.; Betley, T. A.; Peters, J. C. Inorg. Chem., 2007, 46, 5720-5726.

On the Feasibility of N2 Fixation Via a Single Site FeI/FeIV Cycle – Spectroscopic Studies of FeI(N2)FeI, FeIV(N), and Related Species
Hendrich, M. P.; Gunderson, W.; Mehn, M. M.; Betley, T. A.; Lu, C. C.; Behan, R. K.; Green, M. T.; Peters, J. C. Proc. Natl. Acad. Sci. U.S.A., 2006, 103, 17107-17112.

A Tetrahedrally Coordinated L3Fe-Nx Platform that Accommodates Terminal Nitride (FeIVN) and Dinitrogen (FeI-N2) Ligands.
Betley, T. A.; Peters, J. C. J. Am. Chem. Soc., 2004, 126, 6252-6253.

Issues Relevant to C—H Activation at Platinum(II): Comparative Studies between Cationic, Zwitterionic, and Neutral Platinum(II) Compounds in Benzene Solution. Activation and Functionalization of C—H Bonds
Peters, J. C.; Thomas, J. C.; Thomas, C. M.; Betley, T. A., Karen Goldberg and Alan Goldman, eds.; ACS Symposium Series No. 885, 2004, Chapter 20.

Dinitrogen Chemistry from Trigonally Coordinated Iron and Cobalt Platforms
Betley, T. A.; Peters, J. C. J. Am. Chem. Soc., 2003, 125, 10782-10783.

The Strong-Field Tripodal Phosphine Donor, [PhB(CH2PiPr2)3]-, Provides Access to Electronically and Coordinatively Unsaturated Transition Metal Complexes
Betley, T. A.; Peters, J. C. Inorg. Chem., 2003, 42, 5074-5084.

Zwitterionic Relatives to the Classic [(P-P)Rh(solv)2]+ Ions: Neutral Catalysts Active for H—E Bond Additions to Olefins (E = C, Si, B)
Betley, T. A.; Peters, J. C. Angew. Chem. Int. Ed., 2003, 42 2385-2389.

Synthesis of the (Dialkylamino)borate, [Ph2B(CH2NMe2)2]-, Affords Access to N-chelated Rhodium(I) Zwitterions
Betley, T. A.; Peters, J. C. Inorg. Chem., 2002, 41, 6541-6543.